Reactivity of Rhodium(II) amido/Rhodium(I) aminyl complexes
نویسندگان
چکیده
منابع مشابه
Three-coordinate copper(I) amido and aminyl radical complexes.
A three-coordinate Cu-NR(2) system (R = p-tolyl) supported by the anionic bis(phosphino)borate ligand [Ph(2)B(CH(2)P(t)Bu(2))(2)](-) has been isolated and structurally characterized in both its anionic Cu(I) and neutral (formally) Cu(II) oxidation states. A large rate constant for the self-exchange electron-transfer reaction (k(S) >or= 10(7) M(-1) s(-1)) makes this system a functional model for...
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هدف از این مطالعه طراحی یک روش کلی برای سنتز یک سری از کمپلکس های دو هسته ای متقارن سیکلومتاله شده پلاتین (ii) بوده که دارای یک لیگاند پل زن(1,2-bis[bis(pentafluoro-phenyl)phosphino]ethane),dfppe, است. از واکنش cis-[pt(r)2(sme2)2]، که در آنr= para-tolyl ، با یک اکی والان از لیگاند benzo[h]quinoline,bhq، در استون محصول [pt(r)(bhq)(sme2)] که در آن r= para-tolyl بدست می آید. همچنین از واکنش 5/0 اک...
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ژورنال
عنوان ژورنال: Inorganica Chimica Acta
سال: 2018
ISSN: 0020-1693
DOI: 10.1016/j.ica.2018.06.015